extraction titanium solvent

Solvent extraction of titanium(IV) from sulfuric acid …

The extraction behavior of Ti(IV) from sulfuric acid solutions using Cyanex923 has been investigated. The effects of the concentration of H 2 SO 4 and SO 4 2-in the aqueous phase, the extractant concentration in the organic phase, phase ratio, equilibrium time and temperature were studied. Then, the extraction mechanism and …


Highly efficient recovery and purification of scandium

The waste sulfuric acid solution generated from titanium dioxide production is called titanium dioxide waste acid (TWWA), which is an important resource for scandium production. A way including enrichment and purification stages for recovery and purification of Sc from TWWA with 10% P204 - 5% TBP synergistic extraction system was studied.


Extraction of Titanium, Aluminum, and Rare Earth …

Extraction of Titanium, Aluminum, and Rare Earth Values from Upgraded Bauxite Residue. Research Article. Published: 30 March 2023. 9, 665–677 ( 2023 ) …


Recovery and separation of Sc, Zr and Ti from acidic sulfate …

The main composition of acid waste of titanium white production is shown in Table 1.Solvent extraction experiments have been carried out in a pilot-scale countercurrent cascade of mixer-settler type extractors (Fig. 1). For extraction, two countercurrent extraction stages have been used.


A literature review of titanium solvent extraction in chloride …

The solvent extraction results demonstrate that the extracted titanium is present as TiCl4 center dot 2TOPO. The kinetics of the extraction process is very fast, since the equilibrium is reached ...


Sustainable Selective Recovery of Sulfuric Acid and …

A two-stage extraction process was proposed to recover sulfuric acid and vanadium from simulated acid solution and titanium dioxide waste acid (TDWA). Some extractants were compared and studied, in which the enthalpy changes (ΔH) of the extraction process and the extracted complex were analyzed by using thermodynamics. …


Separation and extraction of niobium from H2SO4 solution …

A fluoride-free solvent extraction method for niobium separation in leached sulfuric mother liquor of ilmenorutile was proposed in this paper. The extraction system comprising trioctyl tertiary amine (N235) and 4-methyl-2-pentanone (MIBK) demonstrated good extraction efficiency and selectivity of niobium over titanium and iron impurities in ...


Solvent extraction of titanium(IV) from acidic …

ABSTRACT The extraction of titanium (IV) from hydrochloric acid solutions has been investigated using bis (2,4,4-trimemylpentyl)phosphinic acid (Cyanex 272 = HX) in xylene …


Solvent extraction of titanium from the simulated ilmenite …

DOI: 10.1016/J.HYDROMET.2011.12.023 Corpus ID: 96147564; Solvent extraction of titanium from the simulated ilmenite sulfuric acid leachate by trialkylphosphine oxide @article{Hao2012SolventEO, title={Solvent extraction of titanium from the simulated ilmenite sulfuric acid leachate by trialkylphosphine oxide}, author={Xiaoli Hao and Li …


Separation and Extraction of Scandium and Titanium from …

Under these conditions the extraction percentage of titanium was 78.5% with the extraction equilibrium and phase disengagement times of 40 min and 30 min, respectively.


New understanding of extraction and separation of

Solvent extraction method is extensively used for the separation of vanadium from solutions of multi-metal elements. In the previous study, solvent extraction of vanadium with various extractants such as Cyanex272, LIX63, P507 (EHEHPA) and P204 (D2EHPA) from acidic and alkaline solutions was investigated [9], [10], [11], [12].


Sustainable recovery of titanium from secondary resources: …

The exploitation and utilization of secondary resources have the social benefits of saving resources, reducing pollution, and reducing production costs. Currently, less than 20% of titanium secondary resources can be recycled, and there are few reviews on titanium secondary resources recovery, which cannot fully reveal the technical …


A literature review of titanium metallurgical processes

Selective solvent extraction (SX) step with organic systems such as trioctylphosphine oxide (TOPO) and butyl dibutylphosphonate to separate titanium from impurities of iron, chromium, manganese and niobium. (v) Due to the solvent extraction step, the titania produced has a very high purity (> 99%). (vi)


Scandium Recovery Methods from Mining, Metallurgical …

Solvent extraction and associated technologies such as ion exchange (IX) and liquid ... from 10% to 68.5%, and the iron extraction increases from 1.3% to nearly 5%. Lei et al. devised a way to extract scandium and titanium from red mud leachate solution using a neutralization precipitation and acid leaching methodology as shown in ...


Separation and isolation of tantalum and niobium from …

A fluoride-free solvent extraction method for niobium separation in leached sulfuric mother liquor of ilmenorutile was proposed in this paper. The extraction system comprising trioctyl tertiary amine (N235) and 4-methyl-2-pentanone (MIBK) demonstrated good extraction efficiency and selectivity of niobium over titanium and iron impurities in ...


Solvent extraction of titanium(IV) from sulfuric acid …

Solvent extraction of titanium (IV) from sulfuric acid solution with Cyanex923 and its application in leach liquor of red mud - ScienceDirect. Separation and …


Synthesis of TiO2 nano-powders prepared from purified …

The research work presented in this paper is focused on the development of a purification process of red mud sulphate leach liquor for the recovery of titanium oxide (TiO 2) nano-powders in the form of anatase.Initially, titanium was extracted over iron and aluminium from the leach liquor by solvent extraction using Cyanex 272 in toluene, at …


Enhanced extraction of scandium and inhibiting of iron from …

Gibbs free energy change (ΔG) of −5.93 kJ/mol, enthalpy change (ΔH) of 23.45 kJ/mol and entropy change (ΔH) of 98.54 J/(mol·K) were obtained in the solvent extraction proces, which indicate that the extraction reaction is easily spontaneous and endothermic and a proper increase of temperature is conducive to the extraction of …


Solvent extraction of tetravalent titanium with …

This review discusses the potential for the recovery of titanium using solvent extraction from acidic chloride and sulphate solutions. The aqueous chemistry of titanium and its speciation in...


Solvent Extraction of Scandium from the Waste Solution of …

Solvent extraction of scandium from an aqueous solution of Sc3+–Ti4+–Zr4+, which simulated waste water from the titanium oxide manufacturing process, the Bayers process and others, was performed, and the separation factor of Sc3+ over Ti4+ and Zr4+ was investigated. To clarify the operating conditions of a …


Separation and recovery of scandium and titanium from red …

1. Introduction. Titanium is a rare metal that is dispersed and difficult to extract in nature. Due to its excellent properties such as corrosion resistance and high strength-to-weight ratio, titanium has been widely used in various fields, including aerospace industry, shipbuilding industry, and chemical industry. 1, 2 Scandium is one of …


Metal Extraction with Ionic Liquids-Based Aqueous Two …

1. Introduction. Solvent extraction is the most commonly used method to separate metal ions. This technique is performed by mixing the aqueous phase containing metal salt with an organic phase containing an extraction agent (extractant) [].The simplicity with which the parameters controlling extraction, such as pH of the aqueous solution, …


Solvent Extraction in Metal Hydrometallurgy | SpringerLink

The aqueous–organic solvent extraction system is most applied in metal hydrometallurgy. If a solvent has similar chemical structure as water, the solvent and water will dissolve in each other to cause phase disengagement issues. A solvent less miscible or completely immiscible with water will favor extraction.


A novel method for the separation of niobium and titanium …

A solvent extraction system comprising trioctyl tertiary amine (N235) and 4-methyl-2-pentanone (MIBK) that can extract and separate niobium from an oxalate-containing H 2 SO 4 solution is proposed in this paper. Niobium solutions tend to contain titanium and iron impurities; therefore, the effects of various conditions on the separation …


Solvent extraction of titanium (IV) from sulphuric acid …

Titanium and its compounds found different useful applications in the nuclear and radioactive waste treatment fields. extraction behavior of titanium (IV) from sulfuric acid by commercial tri-octylphosphine oxide (CYANEX 921) and tributylphosphate (TBP)has been investigated. effects of contact time, sulfuric acid concentration in the aqueous …


(PDF) 3‐Phenyl‐4‐acyl‐5‐isoxazolones as …

The solvent extraction results demonstrated that the maximum removal % of Fe(III) was found to be 96 and 92% for Octylamine and N, N-dimethylaniline, respectively, and it was fast, reached ...


Solvent extraction of titanium(IV) from sulfuric acid …

Generally speaking, sulfuric acid is mainly used for the leaching medium of titanium oxide and its ores. And therefore, it is of importance to study the effect of H 2 SO 4 concentration on the extraction of Ti(IV). In our study, the effect of sulfuric acid concentration the extraction of Ti(IV) was investigated within the range of 0.5–3.0 mol.L …


Recovery of scandium from white waste acid generated from the titanium

The scandium concentrate was generated by the solvent extraction from titanium white waste acid from Guangxi Jinmao Titanium Industry Co., Ltd., Guangxi, China. The composition of Sc concentrate was analyzed by X-ray fluorescence (XRF), which confirmed its main components (Ti, Na, Sc, and Zr) and minor impurities (Fe, V, and Mg) …


Solvent extraction of titanium from ilmenite

Sole et al. systematically studied the recovery of titanium from the sulphuric acid leach liquors of titaniferous magnetites by solvent extraction, including part 1. review of the literature and aqueous thermodynamics (Sole, 1999a), part 2. laboratory-scale studies (Sole, 1999b), and part 3. continuous mini-plant trials (Sole et al., 1999).


Solvent extraction of titanium(IV), zirconium(IV) and …

A solvent extraction method is proposed for the extraction of quadrivalent titanium, zirconium and hafnium from salicylate media using liquid ion exchangers such as Aliquat …